Benzaldehyde → HCID 67898655, compound

HRID 1681692Notes

Reaction equation

HRID 1681692 reaction equation
[CH:1](=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl.[Cl:10][C:11]1[CH:12]=[CH:13][C:14]([NH:20][NH2:21])=[C:15]([CH:19]=1)[C:16]([OH:18])=[O:17]>C(O)C.O>[CH:1](=[N:21][NH:20][C:14]1[CH:13]=[CH:12][C:11]([Cl:10])=[CH:19][C:15]=1[C:16]([OH:18])=[O:17])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 2

HCID 240BenzaldehydeHCID 57419260HCID 57419260, compound

Product 1

HCID 67898655HCID 67898655, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

A solution of benzaldehyde (1.48 g) in ethanol (10 ml) was added to a stirred suspension of 5-chloro-2-hydrazinobenzoic acid hydrochloride (described in U.S. Pat. No. 4,105,766; 5.2 g) in water (100 ml). Stirring was continued for 1 hour. The mixture was then left unstirred for 16 hours and then extracted with ether. The extracts were dried (MgSO4) and evaporated to give 2-(benzylidenehydrazino)-5-chlorobenzoic acid (3.5 g) which was used without purification.

Workup

  1. waitThe mixture was then left unstirred for 16 hours
  2. extractionextracted with ether
  3. dry with materialThe extracts were dried (MgSO4)
  4. customevaporated

Sources & evidence

ORD record
ord-067a0f0ae76e4a96b832595892fd6abe
Source dataset
uspto-grants-1992_12
Patent number
US05173496

Reaction notes

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