HRID1683961

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70019

Benzaldehyde, 2,4,6-trimethoxy-

C10H12O4

$结构：COC(=O)C/C(=C\c1ccccc1)C(=O)OC$

HCID6186590

未命名化合物

PRODUCTS

生成物

$结构：COC(=O)C(=C/c1c(OC)cc(OC)cc1OC)/C(=C\c1ccccc1)C(=O)O$

HCID86750969

未命名化合物

$结构：COC(=O)C(=C\c1c(OC)cc(OC)cc1OC)/C(=C\c1ccccc1)C(=O)O$

HCID86750970

未命名化合物

PROCEDURE

实验过程

(E)-3-Methoxycarbonyl-4-phenyl-3-butenoic acid methyl ester and 2,4,6-trimethoxybenzaldehyde are treated in the same manner as in Example 1-(1) to give (E)-2-[(E)-2,4,6-trimethoxybenzylidene]-3-carboxy-4-phenyl-3-butenoic acid methyl ester (foam) and (E)-2-[(Z)-2,4,6-trimethoxybenzylidene]-3-carboxy-4-phenyl-3-butenoic acid methyl ester (m.p. 208°-210° C.).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-df85293bd7a2415c887bb8146776b97d
来源数据集: uspto-grants-1997_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05639789
来源说明: uspto-grants-1997_06

反应 SMILES

[CH3:1][O:2][C:3](=[O:17])[CH2:4]/[C:5](/[C:13]([O:15]C)=[O:14])=[CH:6]\[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.[CH3:18][O:19][C:20]1[CH:27]=[C:26]([O:28][CH3:29])[CH:25]=[C:24]([O:30][CH3:31])[C:21]=1[CH:22]=O>>[CH3:1][O:2][C:3](=[O:17])/[C:4](=[CH:22]/[C:21]1[C:20]([O:19][CH3:18])=[CH:27][C:26]([O:28][CH3:29])=[CH:25][C:24]=1[O:30][CH3:31])/[C:5](/[C:13]([OH:15])=[O:14])=[CH:6]\[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.[CH3:1][O:2][C:3](=[O:17])/[C:4](=[CH:22]\[C:21]1[C:20]([O:19][CH3:18])=[CH:27][C:26]([O:28][CH3:29])=[CH:25][C:24]=1[O:30][CH3:31])/[C:5](/[C:13]([OH:15])=[O:14])=[CH:6]\[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1