Acetic Acid → HCID 86623302, compound

HRID 1684876Notes

Reaction equation

HRID 1684876 reaction equation
[CH3:1][O:2][SiH:3]([O:6][CH3:7])[O:4][CH3:5].C(O)(=O)C.[CH3:12][O:13][CH2:14][O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH:24]=[CH2:25]>O1CCCC1>[CH3:12][O:13][CH2:14][O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][Si:3]([O:6][CH3:7])([O:4][CH3:5])[O:2][CH3:1]

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 17215TrimethoxysilaneHCID 85607836HCID 85607836, compound

Product 1

HCID 86623302HCID 86623302, compoundYield 81.4%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Procedure

Under a nitrogen atmosphere, 64 g of trimethoxysilane and 0.57 g of acetic acid were dropped in a mixture of 100 g of 10-(methoxymethoxy)-1-decene and a catalytic amount of a solution of platinate chloride in tetrahydrofuran at 80° C. The reaction mixture was stirred at 80° C. for 3 hours, and distilled under reduced pressure to yield 131 g of a target compound.

Workup

  1. customat 80° C
  2. distillationdistilled under reduced pressure

Sources & evidence

ORD record
ord-006c75c488e8479f89cd1c49aa06386a
Source dataset
uspto-grants-2012_04
Patent number
US08148053B2

Reaction notes

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