Bicarbonate Ion → 3-Benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

HRID 168636Notes

Reaction equation

HRID 168636 reaction equation
[C:36]([OH:37])([CH3:38])([CH3:39])[CH3:40].[C:47]([OH:48])([CH3:49])([CH3:50])[CH3:51].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:17]2[CH2:18][C:19](=[O:30])[N:20]([CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[S:21]2(=[O:22])=[O:23])[cH:11][cH:12][c:13]([CH:15]=[CH2:16])[cH:14]1.[CH2:31]1[CH2:34][CH2:33][CH2:32][O:35]1.[Na+:46].[O-:42][C:43]([OH:44])=[O:45].[O:53]=[Os:54](=[O:55])(=[O:56])=[O:57].[OH2:41].[OH2:52]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N:17]2[CH2:18][C:19](=[O:30])[N:20]([CH2:24][CH2:25][Si:26]([CH3:27])([CH3:28])[CH3:29])[S:21]2(=[O:22])=[O:23])[cH:11][cH:12][c:13]([CH:15]=[O:35])[cH:14]1

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 962Water2×HCID 6386tert-Butanol2×HCID 8028TetrahydrofuranHCID 30318Osmium TetroxideHCID 667565425-(2-Benzyloxy-4-vinylphenyl)-1,1-dioxo-2-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-3-one

Product 1

HCID 866250473-Benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanylethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Sources & evidence

ORD record
ord-9141416c3f43426385beceacd5b68a2a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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