Gallium → HCID 178521090, compound

HRID 1690835Notes

Reaction equation

HRID 1690835 reaction equation
[Ga:1].[CH2:2]([OH:11])[C@@H:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].CC(C)[O-].[Ga+3].CC(C)[O-].CC(C)[O-]>>[CH2:2]([OH:11])[C@@H:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[Ga:1]

Participants

4

Reactant 3

HCID 5360835GalliumHCID 22253272Gallium (III) isopropoxideHCID 178418489HCID 178418489, compound

Product 1

HCID 178521090HCID 178521090, compound

Procedure

Other 1:1 gallium complexes with polyalcohols can be prepared in a similar fashion by substituting another polyalcohol ligand for the xylitol ligand in this procedure. Similarly, the 2:1 gallium complex with a polyalcohol can be prepared by adding 0.25 mole, instead of 0.5 mole, of polyalcohol ligand to the heated anhydrous gallium isopropoxide solution in this procedure.

Workup

  1. additionby adding 0.25 mole

Sources & evidence

ORD record
ord-f5eb6c67d5314477a85ede477741ebf0
Source dataset
uspto-grants-2012_04
Patent number
US08153687B2

Reaction notes

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