m-Chloroperbenzoic acid → HCID 86638992, compound

HRID 1690866Notes

Reaction equation

HRID 1690866 reaction equation
[C:1]([O:5][C:6](=[O:18])[N:7]([CH2:9][CH2:10][CH2:11][CH:12]1[CH2:17][CH2:16][CH:15]=[CH:14][CH2:13]1)[CH3:8])([CH3:4])([CH3:3])[CH3:2].ClC1C=CC=C(C(OO)=[O:27])C=1>>[C:1]([O:5][C:6](=[O:18])[N:7]([CH3:8])[CH2:9][CH2:10][CH2:11][CH:12]1[CH2:17][CH2:16][CH:15]2[CH:14]([O:27]2)[CH2:13]1)([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 66707773HCID 66707773, compound

Product 1

HCID 86638992HCID 86638992, compoundYield 96.4%

Procedure

(3-Cyclohex-3-enyl-propyl)-methyl-carbamic acid tert-butyl ester (14.24 g, 56.2 mmol) was treated with 3-chloroperbenzoic acid (70% purity, 14.8 g, 60 mmol, corrected) according to the method of Example 7 Step B and stirred for 3 hours at room temperature. After work up the title compound (14.6 g, 96% yield, uncorrected) was obtained as pale yellow oil.

Sources & evidence

ORD record
ord-75c922e03cf44db4afddfa3b27cfdf90
Source dataset
uspto-grants-2012_04
Patent number
US08153689B2

Reaction notes

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