HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Chloro-4-fluoro-1-iodobenzene → (3-Chloro-4-iodophenyl)(methyl)sulfane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Chloro-4-fluoro-1-iodobenzene | HCID 2736559 | — |
| Reactant | Sodium methanethiolate | HCID 4378561 | — |
| Solvent | Water | HCID 962 | — |
| Product | (3-Chloro-4-iodophenyl)(methyl)sulfane | HCID 67280544 | — |
Reaction Steps
Sodium methanethiolate (5 g) was added to a solution of 4-fluoro-2-chloro-iodobenzene (18.3 g) and stirred for 20 h. The mixture was poured into water, extracted with ether, washed with brine, dried (MgSO4) and evaporated. Yield 18.5 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08158820B2 |
| Source dataset | uspto-grants-2012_04 |
| ORD ID | ord-5b56f107b40b48fa941e904a89064b55 |
| Source note | uspto-grants-2012_04 |