Methyl fluorosulfate → HCID 5044326, compound

HRID 1701660Notes

Reaction equation

HRID 1701660 reaction equation
[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][C:3]=1[Cl:18].FS(O[CH3:24])(=O)=O>C1(C)C=CC=CC=1>[Cl:18][C:3]1[CH:4]=[CH:5][C:6]2[C:7](=[O:17])[C:8]3[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=3)[C:14](=[O:16])[C:15]=2[C:2]=1[NH:1][CH3:24]

Participants

4

Reactant 2

HCID 9870Methyl fluorosulfateHCID 670129,10-Anthracenedione, 1-amino-2-chloro-

Product 1

HCID 5044326HCID 5044326, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A solution of 1-amino-2-chloroanthraquinone (2.6 grams; 0.01 mole) and methyl fluorosulfonate (1.254 grams; 0.011 mole) in toluene (50 mls) was refluxed for 22 hours and filtered while hot. The residue in the flask was combined with the filter cake and the combined solids were slurried in 5 N sodium hydroxide at 25° C. for 0.5 hour. The slurry was then filtered, and the solid was rinsed with water and dried. The yield of product obtained was 41% of theoretical.

Workup

  1. filtrationfiltered while hot
  2. filtrationThe slurry was then filtered
  3. washthe solid was rinsed with water
  4. customdried
  5. customThe yield of product obtained

Sources & evidence

ORD record
ord-a8fe9bba19574374b4cbe181623f6bea
Source dataset
uspto-grants-1980_03
Patent number
US04195012

Reaction notes

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