Phenol → HCID 169941, compound

HRID 1701981Notes

Reaction equation

HRID 1701981 reaction equation
[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.O.O.C(O)(=O)[C:11](O)=[O:12].[C:16]([C:24]1[CH:29]=[CH:28][C:27]([OH:30])=[CH:26][CH:25]=1)([CH2:19][C:20]([CH3:23])([CH3:22])[CH3:21])([CH3:18])[CH3:17]>>[C:16]([C:24]1[CH:25]=[CH:26][C:27]([OH:30])=[CH:28][CH:29]=1)([CH2:19][C:20]([CH3:23])([CH3:22])[CH3:21])([CH3:17])[CH3:18].[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:11]=[O:12]

Participants

4

Reactant 3

HCID 996Phenol2×HCID 88144-Tert-octylphenolHCID 61373Oxalic acid dihydrate

Product 1

HCID 169941HCID 169941, compound

Conditions

Temperature
160 °C

Procedure

Phenol (141 g; 1.5 moles) and 2.5 g of oxalic acid dihydrate were added to the resol layer, and the mixture was heated to perform co-condensation reaction of the p-tert-octylphenol resol with phenol. While distilling off the resulting water and volatile matter under atmospheric pressure and then under reduced pressure, the reaction mixture was heated to 160° C. to give 358 g of a pale yellow p-tert-octylphenol/phenol/formaldehyde co-condensate having a softening point of 85° C.

Workup

  1. temperaturethe mixture was heated
  2. distillationWhile distilling off the resulting water and volatile matter under atmospheric pressure

Sources & evidence

ORD record
ord-2f91fa7003a94dedba09820a69b94719
Source dataset
uspto-grants-1983_04
Patent number
US04379897

Reaction notes

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