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HRID1701995

反应详情

EQUATION

反应方程式

HRID 1701995 的结构方程式

REACTANTS

反应物

2
结构：Sc1ccccc1
HCID7969

Benzenethiol

C6H6S

结构：CC(C)(C)C(=O)C=Cc1ccc(Cl)cc1
HCID306049

1-(4-Chlorophenyl)-4,4-dimethylpent-1-en-3-one

C13H15ClO

PRODUCTS

生成物

1
结构：CC(C)(C)C(=O)CC(Sc1ccccc1)c1ccc(Cl)cc1
HCID13048711

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCN(CC)CC
催化剂HCID8471

Triethylamine

C6H15N

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

To a mixture of 4-chlorobenzalpinacolone (22.3 g), triethylamine (5 drops) and ethanol (250 ml) was added thiophenol (12 g) and the mixture was kept to 70° C. for 4 hours. After ice-cooling, the resulted precipitates were collected by filtration, washed with cold ethanol and dried to give white crystals of the captioned compound (29 g; 84%). m.p. 127°-128° C.

WORKUP

后处理

  1. temperatureAfter ice-cooling
  2. customthe resulted precipitates
  3. filtrationwere collected by filtration
  4. washwashed with cold ethanol
  5. customdried
  6. customto give white crystals of the captioned compound (29 g; 84%)