Trichloroisocyanuric Acid → Sulfuric acid magnesium salt (1:1)

HRID 1702128Notes

Reaction equation

HRID 1702128 reaction equation
[O-:1][S:2]([O-:5])(=[O:4])=[O:3].[Mg+2:6].[C:7]([O-:10])([OH:9])=[O:8].[Na+:11].C1(N(Cl)C(=O)N(Cl)C(=O)N1Cl)=O.N(Cl)(Cl)Cl.ClCl>>[S:2]([O-:5])([O-:4])(=[O:3])=[O:1].[Mg+2:6].[C:7](=[O:8])([OH:10])[O-:9].[Na+:11]

Participants

8

Reactant 5

HCID 6909Trichloroisocyanuric AcidHCID 24526ChlorineHCID 61437Nitrogen trichlorideHCID 19385150813-39-3HCID 178435178HCID 178435178, compound

Product 2

HCID 24083Sulfuric acid magnesium salt (1:1)HCID 516892Sodium Bicarbonate

Reagents, catalysts & solvents 1

HCID 178435160HCID 178435160, compoundSolvent

Conditions

Temperature
100 fahrenheit

Procedure

Three mixtures of anhydrous magnesium sulfate, anhydrous sodium bicarbonate and activated carbon were prepared having various weight ratios of the components. The weight ratios of MgSO4 /NaHCO3 /C were 33%:33%:33%; 18%:64%:18%; and 41%:41%18%. Polypropylene scrim packets were filled with 7 grams, 14 grams and 28 grams of each of the mixtures, sealed and enclosed in polyethylene containers holding 1816 grams of TCCA tablets. The containers were stored in a controlled atmosphere maintained at 100° F. and 85 percent relative humidity. Using the method of EXAMPLE 1, head gas analyses determined the percentage of NCl3 and Cl2 present after 14 days. The results are as follows:

Workup

  1. customsealed
  2. custompresent after 14 days

Sources & evidence

ORD record
ord-273ba17a8435402d965da111c2f3c4c1
Source dataset
uspto-grants-1983_04
Patent number
US04380501

Reaction notes

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