Pyridine → HCID 54493129, compound

HRID 1702805Notes

Reaction equation

C1(P(N=[N+]=[N-])(C2C=CC=CC=2)=[O:8])C=CC=CC=1.[CH:18]12[CH2:24][CH:21]([CH:22]=[CH:23]1)[CH2:20][CH:19]2[CH:25]=[CH:26]C(O)=O.[N:30]1[CH:35]=CC=CC=1>>[CH:18]12[CH2:24][CH:21]([CH:22]=[CH:23]1)[CH2:20][CH:19]2[CH:25]=[CH:26][N:30]=[C:35]=[O:8]

Participants

Reactant 3

HCID 1049Pyridine

HCID 858193-(Bicyclo[2.2.1]hept-5-en-2-yl)prop-2-enoic acid

HCID 199401P,P-Diphenylphosphinic azide

Product 1

HCID 54493129HCID 54493129, compound

Conditions

Temperature: 80 °C

Procedure

Diphenylphosphoryl azide (12.1 g.) was added dropwise to a solution of 3-(5-norbornen-2-yl)acrylic acid (6.57 g.) in dry pyridine (30 ml.) and stirred at 80° C. for 30 minutes to give 2-(5-norbornen-2-yl)ethenyl isocyanate (I.R.: 2260 cm-1).

Sources & evidence

ORD record: ord-f245594fd0844007a5b92c5ce56aaf24
Source dataset: uspto-grants-1982_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04349552

Reaction notes

Loading…