Methylamine → 1-Nitro-2-methylamino-2-[2-(2-thiazolylmethylthio)ethylamino]ethylene

HRID 1703605Notes

Reaction equation

HRID 1703605 reaction equation
[N+:1]([CH:4]=[C:5](SC)[NH:6][CH2:7][CH2:8][S:9][CH2:10][C:11]1[S:12][CH:13]=[CH:14][N:15]=1)([O-:3])=[O:2].[CH3:18][NH2:19]>>[N+:1]([CH:4]=[C:5]([NH:19][CH3:18])[NH:6][CH2:7][CH2:8][S:9][CH2:10][C:11]1[S:12][CH:13]=[CH:14][N:15]=1)([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 6329MethylamineHCID 705429481-(Methylsulfanyl)-2-nitro-N-(2-{[(1,3-thiazol-2-yl)methyl]sulfanyl}ethyl)ethen-1-amine

Product 1

HCID 705418401-Nitro-2-methylamino-2-[2-(2-thiazolylmethylthio)ethylamino]ethylene

Procedure

Reaction of 1-nitro-2-methylthio-2-[2-(2-thiazolylmethylthio)ethylamino]ethylene with methylamine according to the process of Example 8(ii) yielded the title compound, m.p. 103°-104°. (from ethanol ether). (Found :C, 39.4; H, 5.2; N,20.2% C9H14N4O2S2 requires: C, 39.4; H, 5.1; N, 20.4%).

Sources & evidence

ORD record
ord-396a7036ae3c4867b6d6be6e3653506d
Source dataset
uspto-grants-1978_11
Patent number
US04124717

Reaction notes

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