HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diazomethane → 6-Pentyl-6-methyl-2-oxo-1,4-oxathiane-3-acetic acid methyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diazomethane | HCID 9550 | — |
| Reactant | 6-Pentyl-6-methyl-2-oxo-1,4-oxathiane-3-acetic acid | HCID 22760772 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 6-Pentyl-6-methyl-2-oxo-1,4-oxathiane-3-acetic acid methyl ester | HCID 54071561 | — |
Reaction Steps
To 4.7 g of 6-pentyl-6-methyl-2-oxo-1,4-oxathiane-3-acetic acid, dissolved in 50 ml of diethyl ether, there is added dropwise, with stirring and ice cooling, ethereal diazomethane solution, until a pale yellow color just remained. After the usual working up, 6-pentyl-6-methyl-2-oxo-1,4-oxathiane-3-acetic acid methyl ester is obtained:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04125622 |
| Source dataset | uspto-grants-1978_11 |
| ORD ID | ord-cc3291d3d0b0448a9faa656b28deb243 |
| Source note | uspto-grants-1978_11 |