N,N'-Diethylthiourea → HCID 22760651, compound

HRID 1703915Notes

Reaction equation

HRID 1703915 reaction equation
[Cl:1][CH2:2][C:3]([C:5]1[CH:10]=[CH:9][C:8]([Cl:11])=[C:7]([S:12](=[O:23])(=[O:22])[NH:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=2[Cl:21])[CH:6]=1)=[O:4].[CH2:24]([NH:26][C:27]([NH:29][CH2:30][CH3:31])=[S:28])[CH3:25]>>[ClH:1].[CH2:30]([N:29]1[C:3]([C:5]2[CH:10]=[CH:9][C:8]([Cl:11])=[C:7]([S:12](=[O:23])(=[O:22])[NH:13][CH2:14][C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=3[Cl:21])[CH:6]=2)([OH:4])[CH2:2][S:28][C:27]1=[N:26][CH2:24][CH3:25])[CH3:31]

Participants

3

Reactant 2

HCID 2735009N,N'-DiethylthioureaHCID 22760471HCID 22760471, compound

Product 1

HCID 22760651HCID 22760651, compound

Procedure

7.8 g of 2,4'-dichloro-3'-o-chlorobenzylsulfamoylacetophenone and 2.5 g of 1,3-diethylthiourea were reacted as prescribed in Example 12 and worked up. Colorless crystals, decomposition beginning at 94° C., γ C=N 1615 cm-1.

Workup

  1. customat 94° C.

Sources & evidence

ORD record
ord-4846e868db5441738d483371d91a2f80
Source dataset
uspto-grants-1978_11
Patent number
US04125614

Reaction notes

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