N,N'-Diethylthiourea → HCID 22760425, compound

HRID 1703924Notes

Reaction equation

HRID 1703924 reaction equation
[Br:1][CH2:2][C:3]([C:5]1[CH:10]=[CH:9][C:8]([Cl:11])=[C:7]([S:12](=[O:17])(=[O:16])[N:13]([CH3:15])[CH3:14])[CH:6]=1)=[O:4].[CH2:18]([NH:20][C:21]([NH:23][CH2:24][CH3:25])=[S:22])[CH3:19]>>[BrH:1].[CH2:24]([N:23]1[C:3]([C:5]2[CH:10]=[CH:9][C:8]([Cl:11])=[C:7]([S:12](=[O:17])(=[O:16])[N:13]([CH3:15])[CH3:14])[CH:6]=2)([OH:4])[CH2:2][S:22][C:21]1=[N:20][CH2:18][CH3:19])[CH3:25]

Participants

3

Reactant 2

HCID 2735009N,N'-DiethylthioureaHCID 204768462-Bromo-4'-chloro-3'-dimethylsulfamoylacetophenone

Product 1

HCID 22760425HCID 22760425, compound

Procedure

6.8 g of 2-bromo-4'-chloro-3'-dimethylsulfamoylacetophenone and 2.7 g of 1,3-diethylthiourea were reacted as prescribed in Example 23. The solvent was decanted and the oily precipitate of the end product was crystallized under fresh acetone. Colorless solid body, decomposition beginning at 154° C., γ C=N 1610 cm-1.

Workup

  1. customThe solvent was decanted
  2. customthe oily precipitate of the end product was crystallized under fresh acetone
  3. customat 154° C.

Sources & evidence

ORD record
ord-707a2d02d1774827b4a0ccb23535691a
Source dataset
uspto-grants-1978_11
Patent number
US04125614

Reaction notes

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