2-Amino-4-methoxy-6-methyl-1,3,5-triazine → HCID 22757974, compound

HRID 1704613Notes

Reaction equation

HRID 1704613 reaction equation
[NH2:1][C:2]1[N:7]=[C:6]([O:8][CH3:9])[N:5]=[C:4]([CH3:10])[N:3]=1.[S:11]1[CH:15]=[CH:14][CH:13]=[C:12]1[S:16]([N:19]=[C:20]=[O:21])(=[O:18])=[O:17]>C(#N)C>[CH3:9][O:8][C:6]1[N:5]=[C:4]([CH3:10])[N:3]=[C:2]([NH:1][C:20]([NH:19][S:16]([C:12]2[S:11][CH:15]=[CH:14][CH:13]=2)(=[O:17])=[O:18])=[O:21])[N:7]=1

Participants

4

Reactant 2

HCID 154662-Amino-4-methoxy-6-methyl-1,3,5-triazineHCID 12875192Thiophene-2-sulfonyl isocyanate

Product 1

HCID 22757974HCID 22757974, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

To a suspension of 14.0 g of 2-amino-4-methoxy-6-methyl-1,3,5-triazine in 300 ml. of acetonitrile was added, dropwise, 19 g of thiophene-2-sulfonyl isocyanate. After stirring for six hours, the mixture was filtered to yield the desired solid product melting at 182°-184° C.

Workup

  1. filtrationthe mixture was filtered

Sources & evidence

ORD record
ord-7e125f107e2246ee9b0b3200d133523b
Source dataset
uspto-grants-1978_11
Patent number
US04127405

Reaction notes

Loading…