Hydrochloric Acid → HCID 22758469, compound

HRID 1704701Notes

Reaction equation

HRID 1704701 reaction equation
[NH2:1][C:2]1[CH:3]=[C:4]([N+:9]([O-:11])=[O:10])[CH:5]=[C:6]([NH2:8])[CH:7]=1.[CH3:12][S:13](Cl)(=[O:15])=[O:14].Cl>N1C=CC=CC=1>[CH3:12][S:13]([NH:1][C:2]1[CH:3]=[C:4]([N+:9]([O-:11])=[O:10])[CH:5]=[C:6]([NH:8][S:13]([CH3:12])(=[O:15])=[O:14])[CH:7]=1)(=[O:15])=[O:14]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 211345-Nitro-1,3-benzenediamineHCID 31297Methanesulfonyl chloride

Product 1

HCID 22758469HCID 22758469, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a solution of 1.5 g. (0.01 mol) of 3,5-diaminonitrobenzene in 3 ml. of pyridine cooled to 5° C. was added 1.6 ml. (0.02 mol) of methanesulfonyl chloride, dropwise, and the mixture was stirred for 90 minutes at room temperature. The reaction mixture was decomposed by adding dilute hydrochloric acid and ice. The solid was filtered, washed with water and dried to give 3,5-bis-methylsulfonamidonitrobenzene, m.p. 223°-224° C.

Workup

  1. additionwas added 1.6 ml
  2. filtrationThe solid was filtered
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-7312bfff7e65457dbfa15204e15d4fd9
Source dataset
uspto-grants-1978_11
Patent number
US04127646

Reaction notes

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