HRID1706153

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC1COC(C)(C)N2C(=O)C(C)(COOC(=O)Cc3ccccc3[N+](=O)[O-])C12

HCID20337377

未命名化合物

HCID20449448

未命名化合物

结构：CC(COC1CCCCO1)C1N(C2CCCCO2)C(=O)C1(C)CO

HCID23333025

未命名化合物

PRODUCTS

生成物

结构：CC(COC1CCCCO1)C1N(C2CCCCO2)C(=O)C1(C)COOC(=O)Cc1ccccc1[N+](=O)[O-]

HCID20337376

未命名化合物

PROCEDURE

实验过程

Following the procedure described for the preparation of 8-oxo-2,2,5,7-tetramethyl-7-(1-o-nitrobenzylcarbonyldioxymethyl)-3-oxa-1-azabicyclo[4.2.0]octane from 8-oxo-2,2,5,7-tetramethyl-7-(1-hydroxymethyl)-3-oxa-1-azabicyclo[4.2.0]octane and using 3-methyl-1-(2-tetrahydropyranyl)-3-(hydroxymethyl)-4-[1-methyl-2-(2-tetrahydropyranyl)oxyethyl]-2-azetidinone there is obtained 3-methyl-1-(2-tetrahydropyranyl)-3-(o-nitrobenzylcarbonyldioxymethyl)-4-[1-methyl-2-(2-tetrahydropyranyl)oxyethyl]-2-azetidinone.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8dfa4ffa18334e2b89da226c6a8a2122
来源数据集: uspto-grants-1980_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04206219
来源说明: uspto-grants-1980_06

反应 SMILES

O=C1N2C(C(C)COC2(C)C)C1(C)CO[O:15][C:16]([CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=1[N+:25]([O-:27])=[O:26])=[O:17].O=C1N2C(C(C)COC2(C)C)C1(C)CO.[CH3:44][C:45]1([CH2:66][OH:67])[CH:48]([CH:49]([CH3:58])[CH2:50][O:51][CH:52]2[CH2:57][CH2:56][CH2:55][CH2:54][O:53]2)[N:47]([CH:59]2[CH2:64][CH2:63][CH2:62][CH2:61][O:60]2)[C:46]1=[O:65]>>[CH3:44][C:45]1([CH2:66][O:67][O:17][C:16]([CH2:18][C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=2[N+:25]([O-:27])=[O:26])=[O:15])[CH:48]([CH:49]([CH3:58])[CH2:50][O:51][CH:52]2[CH2:57][CH2:56][CH2:55][CH2:54][O:53]2)[N:47]([CH:59]2[CH2:64][CH2:63][CH2:62][CH2:61][O:60]2)[C:46]1=[O:65]