Benzene → 1,1-Dichloroethane

HRID 1706856Notes

Reaction equation

HRID 1706856 reaction equation
O.[CH:2]([Cl:5])(Cl)[Cl:3].[C:6]([Cl:10])(Cl)(Cl)[Cl:7].C1C=CC=CC=1>C(Cl)Cl.C1(C)C(C)=CC=CC=1.C1(C)C=CC=CC=1>[Cl:3][CH:2]([Cl:5])[CH3:6].[CH2:2]([Cl:3])[CH:6]([Cl:10])[Cl:7]

Participants

9

Reactant 4

HCID 241BenzeneHCID 962WaterHCID 5943Carbon TetrachlorideHCID 6212Chloroform

Product 2

HCID 63651,1-DichloroethaneHCID 65741,1,2-Trichloroethane

Reagents, catalysts & solvents 3

HCID 1140TolueneSolventHCID 6344DichloromethaneSolventHCID 7237O-XyleneSolvent

Procedure

Suitable stable water-immiscible volatile organic solvents include chlorinated hydrocarbons, such as, in particular methylene chloride, dichloroethane, trichloroethane, chloroform, carbon tetrachloride etc., aromatic hydrocarbons, such as, in particular, benzene, toluene, xylene, etc., and ethers, provided they have a boiling point of less than 45° C. at 1 mm Hg and are immiscible with water.

Sources & evidence

ORD record
ord-9809908614a640f38d67d6e968df4bc7
Source dataset
uspto-grants-1980_06
Patent number
US04209471

Reaction notes

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