Benzonitrile, 3,5-dinitro- → 3-Amino-5-nitrobenzonitrile

HRID 1706933Notes

Reaction equation

HRID 1706933 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[C:10]([N+:12]([O-])=O)[CH:11]=1)[C:7]#[N:8])([O-:3])=[O:2]>[Fe]>[NH2:12][C:10]1[CH:9]=[C:6]([CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:11]=1)[C:7]#[N:8]

Participants

3

Reactant 1

HCID 20062Benzonitrile, 3,5-dinitro-

Product 1

HCID 112289743-Amino-5-nitrobenzonitrile

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

3-amino-5-nitrobenzonitrile is prepared by iron reduction of 3,5-dinitrobenzonitrile as in example 1, m.p. 168°-170° C.

Sources & evidence

ORD record
ord-970f0091b4f04099a459dbadd3e422db
Source dataset
uspto-grants-1980_06
Patent number
US04209528

Reaction notes

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