Diethyl Ether → Dimethyl peroxide

HRID 170701Notes

Reaction equation

HRID 170701 reaction equation
[Br:5][c:6]1[c:7]([OH:17])[cH:8][cH:9][c:10]([CH2:12][O:13][CH2:14][O:15][CH3:16])[cH:11]1.[CH2:24]([Li:25])[CH2:26][CH2:27][CH3:28].[CH3:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23].[CH3:1][O:2][O:3][CH3:4].[CH3:34][CH2:35][O:36][CH2:37][CH3:38].[O:29]=[CH:30][N:31]([CH3:32])[CH3:33]>>[CH3:1][O:2][O:3][CH3:4].[c:6]1([CH:30]=[O:29])[c:7]([OH:17])[cH:8][cH:9][c:10]([CH2:12][O:13][CH2:14][O:15][CH3:16])[cH:11]1

Participants

8

Reactant 6

HCID 3283Diethyl EtherHCID 6228DimethylformamideHCID 8058HexaneHCID 136492Dimethyl peroxideHCID 197016042-Bromo-4-(methoxymethoxymethyl)phenolHCID 178418339Butyllithium

Product 2

HCID 136492Dimethyl peroxideHCID 197015822-Hydroxy-5-(methoxymethoxymethyl)benzaldehyde

Sources & evidence

ORD record
ord-c448717e8c444636bb0b598a5ecc60cc
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

Loading…