5-(4-Chlorophenyl)-2-hydrazinopyridine → HCID 20333397, compound

HRID 1707094Notes

Reaction equation

HRID 1707094 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:9]=[CH:10][C:11]([NH:14][NH2:15])=[N:12][CH:13]=2)=[CH:4][CH:3]=1.[CH:16]([O-])([O-])OCC>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:9]=[CH:10][C:11]3[N:12]([CH:16]=[N:15][N:14]=3)[CH:13]=2)=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 203000925-(4-Chlorophenyl)-2-hydrazinopyridineHCID 53630039Ethylorthoformate

Product 1

HCID 20333397HCID 20333397, compound

Procedure

A mixture of 8.5 g. of 5-(4-chlorophenyl)-2-hydrazinopyridine and 80.0 ml. of ethyl orthoformate is refluxed for 5 hours. The mixture is filtered and the solid is washed with hexane to give 6.5 g. of the product of the Example, m.p. 259°-262° C.

Workup

  1. additionA mixture of 8.5 g
  2. filtrationThe mixture is filtered
  3. washthe solid is washed with hexane
  4. customto give 6.5 g

Sources & evidence

ORD record
ord-ae12a02c2f8d48fd94c9e19c4b51b320
Source dataset
uspto-grants-1980_06
Patent number
US04209626

Reaction notes

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