Ethanol → HCID 86748163, compound

HRID 1707215Notes

Reaction equation

HRID 1707215 reaction equation
[OH:1][C@@H:2]([CH2:6][C:7]([OH:9])=[O:8])[C:3]([OH:5])=[O:4].[CH2:10]([NH2:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.C(O)C>CO>[OH:1][C@@H:2]([CH2:6][C:7]([O-:9])=[O:8])[C:3]([O-:5])=[O:4].[CH2:10]([NH3+:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.[CH2:10]([NH3+:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

5

Reactant 3

HCID 702EthanolHCID 7504BenzylamineHCID 222656L-Malic Acid

Product 1

HCID 86748163HCID 86748163, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

(S)-Hydroxysuccinic acid (3.0 g; 22 mmol) was dissolved in methanol (10 cm3) and added to a mixture of benzylamine (2.2 g; 22 mmol) and ethanol (5 cm3). The resulting white solid was collected by filtration, recrystallized from water and dried in vacuo. Found: C, 54.6%; H, 6.3%; N, 5.8%. Calculated for C11H15NO4 : C, 64.76%; H, 6.28%; N, 5.81%. M.pt. 149°-150° C.

Workup

  1. filtrationThe resulting white solid was collected by filtration
  2. customrecrystallized from water
  3. customdried in vacuo

Sources & evidence

ORD record
ord-344b0cd387b64844afacd23b17911502
Source dataset
uspto-grants-1994_10
Patent number
US05352388

Reaction notes

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