Acrylonitrile → 4-acetyl-5-oxohexanenitrile

HRID 1707341Notes

Reaction equation

[C:1](#[N:4])[CH:2]=[CH2:3].[Na].[C:6]([CH2:9][C:10](=[O:12])[CH3:11])(=[O:8])[CH3:7]>>[C:6]([CH:9]([C:10](=[O:12])[CH3:11])[CH2:3][CH2:2][C:1]#[N:4])(=[O:8])[CH3:7]

Participants

Reactant 3

HCID 7855Acrylonitrile

HCID 31261Acetylacetone

HCID 5360545Sodium

Product 1

HCID 4237844-acetyl-5-oxohexanenitrile

Procedure

4,4-Diacetylbutyronitrile was prepared by addition of acrylonitrile to the sodium salt of acetyl acetone according to the procedure of Johnson et al, J.Chem.Soc (C), 1969, 176.

Sources & evidence

ORD record: ord-9e769141b61146fd83d26413578a0132
Source dataset: uspto-grants-1994_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05352793

Reaction notes

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