1-Nonanol → HCID 86748179, compound

HRID 1707496Notes

Reaction equation

HRID 1707496 reaction equation
[CH3:1][O:2][C:3](=[O:22])[CH:4]([CH3:21])[CH2:5][C:6]1[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:9]([OH:16])=[C:8]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH:7]=1.[CH2:23](O)[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30]C.C([Sn](=O)CCCC)CCC>>[CH2:1]([O:2][C:3](=[O:22])[CH:4]([CH3:21])[CH2:5][C:6]1[CH:7]=[C:8]([C:17]([CH3:20])([CH3:19])[CH3:18])[C:9]([OH:16])=[C:10]([C:12]([CH3:14])([CH3:13])[CH3:15])[CH:11]=1)[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30]

Participants

4

Reactant 3

HCID 89141-NonanolHCID 61221Dibutyltin oxideHCID 18974158HCID 18974158, compound

Product 1

HCID 86748179HCID 86748179, compound

Conditions

Temperature
100 °C

Procedure

30.6 g of methyl-2-methyl-3-(3',5'-di-tert.-butyl-4'-hydroxyphenyl)-propionate and 14.4 g of n-nonyl alcohol are placed in a 100 ml sulfonating flask and heated to 100° C. 0.2 g of dibutyltin oxide is added and the temperature is increased to 150° C. Methyl alcohol is split off from a temperature of 125° C. The reaction is maintained at 150° C. for 6 hours.

Workup

  1. temperaturethe temperature is increased to 150° C
  2. customMethyl alcohol is split off from a temperature of 125° C
  3. temperatureThe reaction is maintained at 150° C. for 6 hours

Sources & evidence

ORD record
ord-fd3e8f56e0564d1bbce075696cd202a1
Source dataset
uspto-grants-1994_10
Patent number
US05354486

Reaction notes

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