1,2-Dichloroethane → HCID 54156050, compound

HRID 1707504Notes

Reaction equation

HRID 1707504 reaction equation
C([SH:3])C.[C:4]([N:9]=[C:10]=[O:11])(=[O:8])[C:5]([CH3:7])=[CH2:6].Cl[CH2:13][CH2:14]Cl>>[C:4]([NH:9][C:10](=[S:3])[O:11][CH2:13][CH3:14])(=[O:8])[C:5]([CH3:7])=[CH2:6]

Participants

4

Reactant 3

HCID 111,2-Dichloroethane2×HCID 6343EthanethiolHCID 10942374Methacryloyl isocyanate

Product 1

HCID 54156050HCID 54156050, compound

Procedure

A solution of ethanethiol (1.24 g; 20 mmol) in 1,2-dichloroethane (12 ml) was dropwise added to a solution of methacryloyl isocyanate (2.22 g; 20 mmol) in 1,2-dichloroethane (14 ml) in 10 minutes under nitrogen stream while cooling with ice. After completion of the addition, the reaction mixture was stirred for 30 minutes. The solvent was removed by evaporation under reduced pressure to give ethyl N-methacryloylthiocarbamate (2.17 g) as a pale yellow liquid. Viscosity, 150 cp.

Workup

  1. temperaturewhile cooling with ice
  2. additionAfter completion of the addition
  3. customThe solvent was removed by evaporation under reduced pressure

Sources & evidence

ORD record
ord-3327ed819a6b43919ac1c5dca6a88a5d
Source dataset
uspto-grants-1994_10
Patent number
US05354495

Reaction notes

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