HuagongsheHuagongshe Chemistry Print Report · For research reference only
((Nonyloxy)methyl)oxirane → 6-(p-Chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | ((Nonyloxy)methyl)oxirane | HCID 99953 | — |
| Reactant | Triphenylethyl phosphonium iodide | HCID 66760890 | — |
| Reactant | 4,4′-[6-(4-Chlorophenyl)-1,3,5-triazine-2,4-diyl]bis[1,3-benzenediol] | HCID 135828187 | — |
| Solvent | Mesitylene | HCID 7947 | — |
| Product | 6-(p-Chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine | HCID 135609948 | — |
Reaction Steps
Following the general procedure of Example 1, 5.0 g (0.015 mol) of 6-(p-chlorophenyl)-2,4-bis-(2,4-dihydroxyphenyl)-s-triazine, 8.0 g (0.036 mol) of glycidyl nonyl ether, 300 mg of triphenylethylphosphonium iodide and 10 mL of mesitylene are reacted at 175° C. for 3.25 hours. The product is worked up by the procedure given in Example 1 to afford 5.6 g (51%) yield of the title compound as a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05354794 |
| Source dataset | uspto-grants-1994_10 |
| ORD ID | ord-67cc834cdd174a4297657abb5e960500 |
| Source note | uspto-grants-1994_10 |