((Nonyloxy)methyl)oxirane → 6-(p-Chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine

HRID 1707827노트

반응식

HRID 1707827 반응식
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[N:13]=[C:12]([C:14]3[CH:19]=[CH:18][C:17]([OH:20])=[CH:16][C:15]=3[OH:21])[N:11]=[C:10]([C:22]3[CH:27]=[CH:26][C:25]([OH:28])=[CH:24][C:23]=3[OH:29])[N:9]=2)=[CH:4][CH:3]=1.[CH2:30]([O:39][CH2:40][CH:41]1[O:43][CH2:42]1)[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38].[I-].C1([C:51]([C:60]2[CH:65]=[CH:64][CH:63]=[CH:62][CH:61]=2)([C:54]2[CH:59]=CC=CC=2)C[PH3+])C=CC=CC=1>C1(C)C=C(C)C=C(C)C=1>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]2[N:9]=[C:10]([C:22]3[CH:27]=[CH:26][C:25]([O:28][CH2:42][CH:41]([OH:43])[CH2:40][O:39][CH2:61][CH2:62][CH2:63][CH2:64][CH2:65][CH2:60][CH2:51][CH2:54][CH3:59])=[CH:24][C:23]=3[OH:29])[N:11]=[C:12]([C:14]3[CH:19]=[CH:18][C:17]([O:20][CH2:42][CH:41]([OH:43])[CH2:40][O:39][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38])=[CH:16][C:15]=3[OH:21])[N:13]=2)=[CH:6][CH:7]=1

참가 물질

5

반응물 3

HCID 99953((Nonyloxy)methyl)oxiraneHCID 66760890Triphenylethyl phosphonium iodideHCID 1358281874,4′-[6-(4-Chlorophenyl)-1,3,5-triazine-2,4-diyl]bis[1,3-benzenediol]

생성물 1

HCID 1356099486-(p-Chlorophenyl)-2,4-bis-[2-hydroxy-4-(2-hydroxy-3-nonyloxypropoxy)phenyl]-s-triazine

시약·촉매·용매 1

HCID 7947Mesitylene용매

실험 절차

Following the general procedure of Example 1, 5.0 g (0.015 mol) of 6-(p-chlorophenyl)-2,4-bis-(2,4-dihydroxyphenyl)-s-triazine, 8.0 g (0.036 mol) of glycidyl nonyl ether, 300 mg of triphenylethylphosphonium iodide and 10 mL of mesitylene are reacted at 175° C. for 3.25 hours. The product is worked up by the procedure given in Example 1 to afford 5.6 g (51%) yield of the title compound as a yellow solid.

후처리

  1. customare reacted at 175° C. for 3.25 hours

출처 및 근거

ORD 기록
ord-67cc834cdd174a4297657abb5e960500
출처 데이터셋
uspto-grants-1994_10
특허 번호
US05354794

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