Methyl iodide → alpha-(Methoxyimino)-alpha-(1-methylpyridinium-3-yl)acetonitrile iodide

HRID 1708108Notes

Reaction equation

HRID 1708108 reaction equation
[CH3:1][O:2][N:3]=[C:4]([C:7]1[CH:8]=[N:9][CH:10]=[CH:11][CH:12]=1)[C:5]#[N:6].[CH3:13][I:14]>CO>[I-:14].[CH3:1][O:2][N:3]=[C:4]([C:7]1[CH:8]=[N+:9]([CH3:13])[CH:10]=[CH:11][CH:12]=1)[C:5]#[N:6]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 53756267HCID 53756267, compound

Product 1

HCID 85648911alpha-(Methoxyimino)-alpha-(1-methylpyridinium-3-yl)acetonitrile iodideYield 100%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

α-(Methoxyimino)-α-(pyridin-3-yl)acetonitrile (D4) (0.155 g, 0.00096 mol) was heated under reflux with methyl iodide (5 ml) in methanol (5 ml) for 60 h. The mixture was evaporated to dryness to give the title compound (D6) (0.3 g, 100%) which was used without further purification.

Workup

  1. customThe mixture was evaporated to dryness

Sources & evidence

ORD record
ord-c7340191ffc64b83afc8c973417d2fb9
Source dataset
uspto-grants-1994_10
Patent number
US05356914

Reaction notes

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