HRID1708626

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24758

Sodium hydride

HNa

HCID11322811

1-Cyclohexyloxy-2,2,6,6-tetramethyl-piperidin-4-ol

C15H29NO2

HCID53986730

未命名化合物

PRODUCTS

生成物

结构：CC1(C)CC(OCC(O)COC2CC(C)(C)N(OC3CCCCC3)C(C)(C)C2)CC(C)(C)N1OC1CCCCC1

HCID18959463

未命名化合物

PROCEDURE

实验过程

The title compound is prepared by the reaction of 1-(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yloxy)-2,3-epoxypropane (prepared in Example 11) with 4-hydroxy-1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine (prepared in Example 5) and sodium hydride.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-244948e41553488a949172135c927032
来源数据集: uspto-grants-1994_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05359069
来源说明: uspto-grants-1994_10

反应 SMILES

[CH2:1]([O:9][N:10]1[C:15]([CH3:17])([CH3:16])[CH2:14][CH:13]([O:18][CH2:19][CH:20]2[O:22][CH2:21]2)[CH2:12][C:11]1([CH3:24])[CH3:23])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]CC.[OH:25][CH:26]1[CH2:31][C:30]([CH3:33])([CH3:32])[N:29]([O:34][CH:35]2[CH2:40][CH2:39][CH2:38][CH2:37][CH2:36]2)[C:28]([CH3:42])([CH3:41])[CH2:27]1.[H-].[Na+]>>[CH:1]1([O:9][N:10]2[C:15]([CH3:16])([CH3:17])[CH2:14][CH:13]([O:18][CH2:19][CH:20]([OH:22])[CH2:21][O:25][CH:26]3[CH2:31][C:30]([CH3:32])([CH3:33])[N:29]([O:34][CH:35]4[CH2:40][CH2:39][CH2:38][CH2:37][CH2:36]4)[C:28]([CH3:42])([CH3:41])[CH2:27]3)[CH2:12][C:11]2([CH3:24])[CH3:23])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1