Chlorotrimethylsilane → HCID 15219057, compound

HRID 1708656Notes

Reaction equation

HRID 1708656 reaction equation
[CH:1]1([Si:6]([O:13][CH2:14][CH3:15])([O:10][CH2:11][CH3:12])[O:7][CH2:8][CH3:9])[CH2:5][CH2:4][CH2:3][CH2:2]1.[CH:16](O)(CC)[CH3:17].C[Si](C)(C)Cl>[O-]CC.[Na+]>[CH:11]([O:10][Si:6]([CH:1]1[CH2:2][CH2:3][CH2:4][CH2:5]1)([O:13][CH2:14][CH3:15])[O:7][CH2:8][CH3:9])([CH2:16][CH3:17])[CH3:12]

Participants

5

Reactant 3

HCID 6397ChlorotrimethylsilaneHCID 6568(+-)-2-ButanolHCID 16217491Cyclopentyl(triethoxy)silane

Product 1

HCID 15219057HCID 15219057, compoundYield 73.3%

Reagents, catalysts & solvents 1

HCID 2723922Sodium ethoxideCatalyst

Procedure

In a 500 ml three-neck flask provided with a magnetic stirrer and a reflux condenser were charged 29.6 g (0.127 mole) of cyclopentyl triethoxysilane, 151.1 g (2.04 mole) of sec-butyl alcohol and 286.5 mg (4.21 m mole) of sodium ethoxide, which were then reacted with each other in an oil bath of 50° C. for 10 hours under stirring. Then, trimethylchlorosilane was added to neutralize the alkali. Then, 24.2 g (0.0931 mole) of sec-butoxy cyclopentyl diethoxysilane were obtained by vacuum distillation. Its structure was confirmed as in Example 1. The yield was 73%

Workup

  1. customIn a 500 ml three-neck flask provided with a magnetic stirrer and a reflux condenser
  2. customwere then reacted with each other in an oil bath of 50° C. for 10 hours

Sources & evidence

ORD record
ord-5d569b04d0894c1e997b669ed1413d15
Source dataset
uspto-grants-1994_10
Patent number
US05359114

Reaction notes

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