HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lithium Chloride → 1,1,1,2,2,3,3-Heptafluoro-4-chlorobutane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lithium Chloride | HCID 433294 | — |
| Reactant | 2,2,3,3,4,4,4-Heptafluorobutyl 4-methylbenzene-1-sulfonate | HCID 2063399 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | 1,1,1,2,2,3,3-Heptafluoro-4-chlorobutane | HCID 136218 | — |
Reaction Steps
For example, to prepare 1,1-dichloro-2,2,3,3,4,4,4-heptafluorobutane, 2,2,3,3,4,4,4-heptafluorobutanol and p-toluenesulfonyl chloride are reacted to form 2,2,3,3,4,4,4-heptafluorobutyl-p-toluenesulfonate. Then, N-methylpyrrolidone, lithium chloride, and the 2,2,3,3,4,4,4-heptafluorobutyl-p-toluenesulfonate are reacted to form 1-chloro-2,2,3,3,4,4,4-heptafluorobutane. Finally, chlorine and the 1-chloro-2,2,3,3,4,4,4-heptafluorobutane are reacted to form the 1,1-dichloro-2,2,3,3,4,4,4-heptafluorobutane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04947881 |
| Source dataset | uspto-grants-1990_08 |
| ORD ID | ord-997433fad7724175b606552a18582063 |
| Source note | uspto-grants-1990_08 |