Thionyl Chloride → HCID 23037260, compound

HRID 1709258Notes

Reaction equation

HRID 1709258 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6](/[CH:9]=[CH:10]/[CH2:11]O)=[CH:5][C:4]=1[N+:13]([O-:15])=[O:14].S(Cl)([Cl:18])=O>C(Cl)Cl>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6](/[CH:9]=[CH:10]/[CH2:11][Cl:18])=[CH:5][C:4]=1[N+:13]([O-:15])=[O:14]

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 148356852-Propen-1-ol, 3-(4-methoxy-3-nitrophenyl)-, (E)-

Product 1

HCID 23037260HCID 23037260, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.09 g of (E)-(4-methoxy-3-nitrophenyl)allyl alcohol was dissolved in 21 ml of methylene chloride. To the solution was added 1.79 g of thionyl chloride with ice-cooling. The mixture was stirred for 1 hour at room temperature. The solvent was removed by distillation under reduced pressure to obtain crystals of (E)-3-(4-methoxy-3-nitrophenyl)allyl chloride. The crystals were dissolved in 10 ml of methylene chloride.

Workup

  1. temperaturecooling
  2. customThe solvent was removed by distillation under reduced pressure

Sources & evidence

ORD record
ord-34aaeb1a06444ac994aec1f1b28d1969
Source dataset
uspto-grants-1990_08
Patent number
US04948796

Reaction notes

Loading…