Thiirane → HCID 23035052, compound

HRID 1709952Notes

Reaction equation

HRID 1709952 reaction equation
[N:1]1[CH:6]=[CH:5][C:4]([CH2:7][NH:8][S:9](=[O:12])(=[O:11])[OH:10])=[CH:3][CH:2]=1.[OH-].[Na+].[CH2:15]1[S:17][CH2:16]1>O.[N+]([O-])([O-])=O.[Ag+]>[OH-:10].[SH:17][CH2:16][CH2:15][N+:1]1[CH:6]=[CH:5][C:4]([CH2:7][NH:8][S:9]([OH:10])(=[O:11])=[O:12])=[CH:3][CH:2]=1

Participants

6

Reactant 3

HCID 9865ThiiraneHCID 14798Sodium HydroxideHCID 14851075N-(4-Pyridinylmethyl)sulfamic acid

Product 1

HCID 23035052HCID 23035052, compound

Reagents, catalysts & solvents 2

HCID 24470Silver NitrateCatalystHCID 962WaterSolvent3×

Procedure

A suspension of N-(4-pyridylmethyl)sulfamic acid (800 ml, 4.25 mmol) in water (5.0 ml) was adjusted to pH 7.0 with aqueous sodium hydroxide solution (2.5N). The resulting solution was treated with a solution of silver nitrate (723 ml, 4.25 mmol) in water (3.0 ml) to give a white suspension. Additional water (5.0 ml) was added to facilitate stirring and the mixture was treated with ethylene sulfide (0.280 ml, 4.67 mmol).

Workup

  1. customto give a white suspension

Sources & evidence

ORD record
ord-0b6be3345aee4f838df315dd71008754
Source dataset
uspto-grants-1990_08
Patent number
US04952397

Reaction notes

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