HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → (-) 4,4,5-Trimethyl 2-phenyl 1,3,2-dioxaphospholane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Triethylamine hydrochloride | HCID 11130 | — |
| Reactant | Phenyl phosphorus dichloride | HCID 12573 | — |
| Reactant | 2-Methyl-2,3-butanediol | HCID 95362 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | (-) 4,4,5-Trimethyl 2-phenyl 1,3,2-dioxaphospholane | HCID 13904591 | — |
Reaction Steps
5 g of (+)2 methyl butane 2,3-diol, ##STR24## are mixed with 8.6 g of dichlorophenylphosphin at 0° C. under stirring in 250 ml of dry toluene, in an atmosphere. Then 10.2 g of triethylamine are added within a few minutes. After 1 hour of reaction triethylamine hydrochloride is formed; it is separated by filtration and the toluene solvent is vaporized.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04952740 |
| Source dataset | uspto-grants-1990_08 |
| ORD ID | ord-417867ea9d214e35b6c043ca5c25419c |
| Source note | uspto-grants-1990_08 |