Azido(trimethyl)stannane → HCID 58754854, compound

HRID 1711318Notes

Reaction equation

HRID 1711318 reaction equation
[NH2:1][C:2]1[CH:9]=[CH:8][C:5]([C:6]#[N:7])=[CH:4][C:3]=1[C:10]1[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]=1.[N:16]([Sn:19]([CH3:22])([CH3:21])[CH3:20])=[N+:17]=[N-:18]>>[C:10]1([C:3]2[CH:4]=[C:5]([C:6]3[N:16]([Sn:19]([CH3:22])([CH3:21])[CH3:20])[N:17]=[N:18][N:7]=3)[CH:8]=[CH:9][C:2]=2[NH2:1])[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]=1

Participants

3

Reactant 2

HCID 5104973Azido(trimethyl)stannaneHCID 68507674HCID 68507674, compound

Product 1

HCID 58754854HCID 58754854, compound

Procedure

The title compound was prepared from 4-amino-3-cyclohex-1-enyl-benzonitrile (as prepared in the previous step, 245 mg, 0.123 mmol) and azidotrimethylstannane (267 mg, 1.29 mmol) according to the procedure in Example 52, step (c) (320 mg, 64%). Mass spectrum (ESI, m/z): Calcd. for C13H15N5, 242.1 (M-SnMe3+2H), found 242.2 (M+H).

Sources & evidence

ORD record
ord-42d8e5a4024742a7aaf7b92baf8479c8
Source dataset
uspto-grants-2010_09
Patent number
US07790724B2

Reaction notes

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