Acetic Acid → HCID 23146832, compound

HRID 1715534Notes

Reaction equation

HRID 1715534 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([NH2:8])[C:3]=1[NH2:9].[CH:10]1[C:23]2[C:22](=O)[C:21](=O)[C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[C:14]=2[CH:13]=[CH:12][CH:11]=1.C(O)(=O)C>CO>[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]2[C:3]=1[N:9]=[C:21]1[C:22](=[N:8]2)[C:23]2[CH:10]=[CH:11][CH:12]=[CH:13][C:14]=2[C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][C:20]1=2

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 67639,10-PhenanthrenedioneHCID 690991,2,3-Triaminobenzene

Product 1

HCID 23146832HCID 23146832, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

10.1 g (82 mmol) of 1,2,3-triaminobenzene and 14.6 g (70 mmol) of 9,10-phenanthrenequinone were placed in a four-necked flask, to which 350 g of a solvent of acetic acid and methanol at 1:1 was added for dissolution, followed by reaction at a reaction temperature of 70° C. for 2 hours. After the reaction, the solvent was removed and the resulting product was washed with methanol to obtain the intended product.

Workup

  1. additionwas added for dissolution
  2. customfollowed by reaction at a reaction temperature of 70° C. for 2 hours
  3. customAfter the reaction
  4. customthe solvent was removed
  5. washthe resulting product was washed with methanol
  6. customto obtain the intended product

Sources & evidence

ORD record
ord-87f5712606154b728adbf2e501ec95ad
Source dataset
uspto-grants-2010_09
Patent number
US07799894B2

Reaction notes

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