Aniline → HCID 57864785, compound

HRID 1715874Notes

Reaction equation

HRID 1715874 reaction equation
[I:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:17]2[CH:22]=[CH:21][C:20]([I:23])=[CH:19][CH:18]=2)([C:10]2[CH:15]=[CH:14][C:13]([I:16])=[CH:12][CH:11]=2)O)=[CH:4][CH:3]=1.[NH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>C(O)C>[NH2:24][C:25]1[CH:30]=[CH:29][C:28]([C:8]([C:17]2[CH:22]=[CH:21][C:20]([I:23])=[CH:19][CH:18]=2)([C:10]2[CH:15]=[CH:14][C:13]([I:16])=[CH:12][CH:11]=2)[C:5]2[CH:6]=[CH:7][C:2]([I:1])=[CH:3][CH:4]=2)=[CH:27][CH:26]=1

Participants

4

Reactant 2

HCID 6115AnilineHCID 57864781HCID 57864781, compound

Product 1

HCID 57864785HCID 57864785, compoundYield 93%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Conditions

Temperature
190 °C

Procedure

89 parts by weight of tris(4-iodophenyl)methanol and 500 parts by weight of aniline were put into a reaction vessel and stirred for 4 hours while heating at 190° C. 350 parts by weight of ethanol was added thereto, and stirring was carried out for 1 hour while heating at 90° C. After cooling, a deposited solid was collected by filtration and washed with methanol, thus giving 100 parts by weight of 4-aminophenyl[tris(4-iodophenyl)]methane (yield: 93%).

Workup

  1. stirringstirring
  2. waitwas carried out for 1 hour
  3. temperaturewhile heating at 90° C
  4. temperatureAfter cooling
  5. filtrationa deposited solid was collected by filtration
  6. washwashed with methanol

Sources & evidence

ORD record
ord-ca0308c1eb54413ab9454931e69eb30e
Source dataset
uspto-grants-2010_09
Patent number
US07799949B2

Reaction notes

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