Acetic Acid → HCID 23146832, compound

HRID 1717224Notes

Reaction equation

HRID 1717224 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([NH2:8])[C:3]=1[NH2:9].[CH:10]1[C:23]2[C:22](=O)[C:21](=O)[C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[C:14]=2[CH:13]=[CH:12][CH:11]=1.C(O)(=O)C>CO>[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]2[C:3]=1[N:9]=[C:21]1[C:22](=[N:8]2)[C:23]2[CH:10]=[CH:11][CH:12]=[CH:13][C:14]=2[C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][C:20]1=2

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 67639,10-PhenanthrenedioneHCID 690991,2,3-Triaminobenzene

Product 1

HCID 23146832HCID 23146832, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

10.1 g (82 mmol) of 1,2,3-triaminobenzene and 4.6 g (70 mmol) of 9,10-phenanthrenequinone were placed in a four-necked flask, to which 350 g of a solvent of acetic acid and methanol at 1:1 was added for dissolution, followed by reaction at a reaction temperature of 70° C. for 2 hours. After the reaction, the solvent was removed and the resulting product was washed with methanol to obtain the intended product.

Workup

  1. additionwas added for dissolution
  2. customfollowed by reaction at a reaction temperature of 70° C. for 2 hours
  3. customAfter the reaction
  4. customthe solvent was removed
  5. washthe resulting product was washed with methanol
  6. customto obtain the intended product

Sources & evidence

ORD record
ord-48038dfde12b41a18a43c9eb84f81904
Source dataset
uspto-grants-2010_09
Patent number
US07803898B2

Reaction notes

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