Water → HCID 13326123, compound

HRID 1719112Notes

Reaction equation

HRID 1719112 reaction equation
S(C1C=CC(C)=CC=1)([O-])(=O)=O.[Cl:12][C:13]1[CH:35]=[C:34]([Cl:36])[CH:33]=[CH:32][C:14]=1[O:15][CH:16]([O:23][C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][C:25]=1[Cl:31])[CH:17](O)[C:18]([CH3:21])([CH3:20])[CH3:19].O>CS(C)=O>[Cl:12][C:13]1[CH:35]=[C:34]([Cl:36])[CH:33]=[CH:32][C:14]=1[O:15][C:16]([O:23][C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][C:25]=1[Cl:31])=[CH:17][C:18]([CH3:20])([CH3:21])[CH3:19]

Participants

5

Reactant 3

HCID 962WaterHCID 85570p-ToluenesulfonateHCID 13326121HCID 13326121, compound

Product 1

HCID 13326123HCID 13326123, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

54.6 g (0.1 mole) of the tosylate of 1,1-bis-(2,4-dichlorophenoxy)-3,3-dimethylbutan-2-ol in 200 ml of dry dimethylsulfoxide were mixed with an equimolar amount of potassium tert.-butylate. The mixture was stirred for 30 minutes at room temperature, after which hydrolysis was effected with water, the mixture was extracted twice with the same volume of ethyl acetate, the extracts were dried and the solvent was distilled off under reduced pressure.

Workup

  1. customafter which hydrolysis
  2. extractionthe mixture was extracted twice with the same volume of ethyl acetate
  3. customthe extracts were dried
  4. distillationthe solvent was distilled off under reduced pressure

Sources & evidence

ORD record
ord-6cc0768ecb314a34b61d557537e97477
Source dataset
uspto-grants-1985_09
Patent number
US04539160

Reaction notes

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