HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1719203Generated: November 2, 2026
Hydrogen Peroxide → 2-Methyl-1lambda~4~,4-thiazinane-1,3-dione
https://huagongshe.com/reaction/1719203
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | 2-Methyl-thioMorpholin-3-one | HCID 95528 | — |
| Solvent | Formic Acid | HCID 284 | — |
| Solvent | Acetic Anhydride | HCID 7918 | — |
| Product | 2-Methyl-1lambda~4~,4-thiazinane-1,3-dione | HCID 70499313 | — |
Reaction Steps
To a solution of 9 g of 2-methyl-3-thiamorpholinone in a mixture of 50 cm3 of formic acid and 10 cm3 of acetic anhydride, cooled to 0° C., 7 cm3 of H2O2 at 110 vol. are slowly added. After an 18 hour reaction period, the solution is concentrated under reduced pressure. The resulting product is dissolved in chloroform and the chloroform solution is deposited on a silica gel column.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04539320 |
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| Source dataset | uspto-grants-1985_09 |
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| ORD ID | ord-9e1cfce60b6e4b108c1b6d2dfc7f2bf2 |
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| Source note | uspto-grants-1985_09 |
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