Ammonia → HCID 57152418, compound

HRID 1719455Notes

Reaction equation

HRID 1719455 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][NH:5][P:6](Cl)(Cl)=[O:7].[NH3:10].[NH4+:11].[Cl-]>C(Cl)Cl>[Br:1][CH2:2][CH2:3][CH2:4][NH:5][P:6](=[O:7])([NH2:11])[NH2:10]

Participants

5

Reactant 3

HCID 222AmmoniaHCID 25517Ammonium ChlorideHCID 20266877HCID 20266877, compound

Product 1

HCID 57152418HCID 57152418, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The crude 3-bromopropylphosphoramidic dichloride was added to a solution of 10 g of ammonia in 125 mL CH2Cl2 at -30° C. The resulting mixture of product and NH4Cl weighed 19.4 g. Extraction with CH2Cl2 gave a material which slowly discolored over several days, mp. 60°-65° C.

Workup

  1. extractionExtraction with CH2Cl2
  2. customgave a material which
  3. waitslowly discolored over several days

Sources & evidence

ORD record
ord-fad859f556494300ba1a37e26faa7d65
Source dataset
uspto-grants-1985_09
Patent number
US04540428

Reaction notes

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