1,3-Dimethyl-2-imidazolidinone → 3-Phenoxybenzyl alcohol

HRID 1719799Notes

Reaction equation

HRID 1719799 reaction equation
CN1CCN(C)[C:3]1=[O:8].Cl[C:10]1[CH:11]=[C:12](C(C)(C)CCl)[CH:13]=[CH:14][C:15]=1[O:16][CH2:17][CH3:18]>>[O:16]([C:15]1[CH:10]=[C:11]([CH:12]=[CH:13][CH:14]=1)[CH2:3][OH:8])[C:17]1[CH:18]=[CH:14][CH:15]=[CH:10][CH:11]=1

Participants

3

Reactant 2

HCID 66611,3-Dimethyl-2-imidazolidinone2×HCID 52687462-Chloro-4-(2-chloro-1,1-dimethylethyl)-1-ethoxybenzene

Product 1

HCID 262953-Phenoxybenzyl alcoholYield 500%

Procedure

3 l (3,156 g) of 1,3-dimethyl-2-imidazolidinone (hereinafter referred to as DMI), 618.0 g (2.50 mol) of purified 2-(3-chloro-4-ethoxyphenyl)-2-methylpropyl chloride obtained in the same manner as in Example 1, 1,251.0 g (6.25 mol) of m-phenoxybenzyl alcohol (a product of Ethyl Corp.) and 280.0 g (5.00 mol) of potassium hydroxide in the form of flakes were charged in a 5 l four-neck flask and stirred at 120° C. under nitrogen stream for 15 h to complete the reaction.

Sources & evidence

ORD record
ord-e98a9814729042de9c6966ebdf21f885
Source dataset
uspto-grants-1985_09
Patent number
US04542243

Reaction notes

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