Indole → 24046-71-7

HRID 1720569Notes

Reaction equation

HRID 1720569 reaction equation
N1C2C(=CC=CC=2)C=C1.[NH2:10][C@H:11]([C:13]([OH:15])=[O:14])[CH3:12].[H][H].N1C2C(=CC=CC=2)C=C1.[NH2:27][C@H:28]([C:39](O)=[O:40])[CH2:29][C:30]1[C:38]2[C:33](=[CH:34][CH:35]=[CH:36][CH:37]=2)[NH:32][CH:31]=1>>[CH3:12][C@H:11]([NH:10][C:39]([C@@H:28]([NH2:27])[CH2:29][C:30]1[C:38]2[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=2[NH:32][CH:31]=1)=[O:40])[C:13]([OH:15])=[O:14]

Participants

5

Reactant 4

HCID 798Indole5×HCID 5950L-AlanineHCID 6305L-Tryptophan4×HCID 178506442HCID 178506442, compound

Product 1

HCID 699340124046-71-7

Procedure

NMR (1H) in DMSO-d6 10.92 (1H, s) NH indole, 8.45 (1H, broad s) NH Ala, 7.63 (1H, d) H4 indole, 7.32 (1H, d) H7 indole, 7.20 (1H, s) H2 indole, 7.05 (1H, t) H6 indole, 6.97 (1H, t) H5 indole, 4.16 (1H, broad q) HαAla, 3.76 (1H, dd) Hα Trp, 3.19 (1H, dd) HβA Trp, 2.90 (1H, dd) HβB Trp, 1.25 (1H, t) CH3 Ala

Sources & evidence

ORD record
ord-31a8b3b827b0490bab53cbcfbd0ed103
Source dataset
uspto-grants-1996_04
Patent number
US05506362

Reaction notes

Loading…