HRID1721476

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID795

Imidazole

C3H4N2

HCID28928

Chloro(1,1-dimethylethyl)dimethylsilane

C6H15ClSi

结构：CO[C@H]1OC(CO)[C@H](O)[C@@H](O)[C@@H]1O

HCID76607

未命名化合物

结构：CO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1NC(C)=O

HCID445750

N-[(2R,3R,4R,5S,6R)-4,5-Dihydroxy-6-(hydroxymethyl)-2-methoxyoxan-3-yl]acetamide

C9H17NO6

结构：CO[C@@H]1C[C@@H](O)[C@H](O)[C@@H](CO)O1

HCID9920525

未命名化合物

PRODUCTS

生成物

结构：CO[C@@]1(C)O[C@H](COC(C)(C)C)[C@@H](O)[C@H](O)[C@H]1C

HCID53829532

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

This compound was prepared from the corresponding methyl glucoside, Methyl 2-deoxy-α-D-glucopyranoside. (Carbohydrates, Ed. Collins, P. M., Chapman and Hall, New York, 1987. p. 352) by treatment with t-butyldimethylchlorosilane in DMF and imidazole. 1H NMR δ4.73 (d, 1, J=3 Hz), 3.85-3.78 (M, 4), 3.55-3.46 (m, 2), 3.35 (m, 1), 3.29 (s, 3), 2.05 (m, 1), 1.61 (m, 1), 0.88 (m, 9), 0.07 (m, 6).