Diisopropyl Ether → HCID 15631698, compound

HRID 1721932Notes

Reaction equation

[Cl:1][C:2]1[C:14]([Cl:15])=[C:13]([C:16]([C:18]2[N:22](COCC)[N:21]=[CH:20][CH:19]=2)=[CH2:17])[CH:12]=[CH:11][C:3]=1[O:4][CH2:5][C:6]([O:8][CH2:9][CH3:10])=[O:7].C(OC(C)C)(C)C>>[Cl:1][C:2]1[C:14]([Cl:15])=[C:13]([C:16]([C:18]2[NH:22][N:21]=[CH:20][CH:19]=2)=[CH2:17])[CH:12]=[CH:11][C:3]=1[O:4][CH2:5][C:6]([O:8][CH2:9][CH3:10])=[O:7]

Participants

Reactant 2

HCID 7914Diisopropyl Ether

HCID 15631689HCID 15631689, compound

Product 1

HCID 15631698HCID 15631698, compoundYield 86.2%

Procedure

1.10 g of ethyl {2,3-dichloro-4-[1-(1-ethoxymethyl-5-pyrazolyl)vinyl]phenoxy}acetate are treated in the same manner as described in Example 35 except that isopropyl ether is used as the crystallization solvent. 0.81 g of ethyl {2,3-dichloro-4-[1-(5-pyrazolyl)vinyl]phenoxy}acetate is obtained as crystals.

Sources & evidence

ORD record: ord-9d103a8b21e64159826293b186df74c1
Source dataset: uspto-grants-1989_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04853404

Reaction notes

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