HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Nitrophenol → methylphosphonothioic acid O,O-bis-(4-nitrophenyl)ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Nitrophenol | HCID 980 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Phosphonothioic dichloride, methyl- | HCID 61195 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | methylphosphonothioic acid O,O-bis-(4-nitrophenyl)ester | HCID 11416910 | — |
Reaction Steps
The methylphosphonothioic acid O,O-bis-(4-nitrophenyl)ester intermediate is prepared according to procedure E using 536 mg of methylphosphonothioic dichloride, 345 mg of sodium hydride (50% in oil), 1 g of p-nitrophenol and 10 ml of tetrahydrofuran. 1.19 g of expected product are collected.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07491710B2 |
| Source dataset | uspto-grants-2009_02 |
| ORD ID | ord-fab672fb80b0443887739619f7806018 |
| Source note | uspto-grants-2009_02 |