HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 86595689, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 6-Chloro-1-hexanol | HCID 74828 | — |
| Reactant | ethyl N-ethoxycarbonyliminocarbamate | HCID 220568 | — |
| Reactant | Umbelliferone | HCID 5281426 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 86595689 | HCID 86595689 | — |
Reaction Steps
Preparation can be carried out analogously to Synthetic Example 1 using 16.2 g (100 mmol) 7-Hydroxycoumarin, 14.3 g (105 mmol) 6-chlorohexanol, 28.8 g (110 mmol) triphenylphosphine and 47.9 g (110 mmol) of a 40% solution of azodicarboxylic acid diethyl ester in toluene to yielded 7-(6-chlorohexyl) coumarin.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07491752B2 |
| Source dataset | uspto-grants-2009_02 |
| ORD ID | ord-43cb210687cc421287200db87b4e9930 |
| Source note | uspto-grants-2009_02 |