HRID1728255

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11430

Potassium Carbonate

CK2O3

HCID76701

Propane, 1,3-dibromo-2,2-bis(bromomethyl)-

C5H8Br4

HCID135617152

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCc1cnc(-c2ccc(OCC(COc3ccc(-c4ncc(CCCCCCC)cn4)cc3)(COc3ccc(-c4ncc(CCCCCCC)cn4)cc3)COc3ccc(-c4ncc(CCCCCCC)cn4)cc3)cc2)nc1

HCID14985161

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID679

Dimethyl sulfoxide

C2H6OS

CONDITIONS

反应条件

温度: 80 °C

PROCEDURE

实验过程

) 5.0 g of the known compound 4-(5-heptyl-2-pyrimidyl)phenol are dissolved in 70 ml of dimethyl sulfoxide together with 1.35 g of pentaerythrityl tetrabromide. 15 g of finely powdered potassium carbonate are added, and the mixture is stirred at 80° C. for 16 h. Conventional work-up gives 2.1 g of tetrakis[4-(5-heptyl-2-pyrimidyl)phenyloxymethyl]methane, m.p. 179°.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8fcbefeb836545cfabeca3e9a65c7584
来源数据集: uspto-grants-1994_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05326495
来源说明: uspto-grants-1994_07

反应 SMILES

[CH2:1]([C:8]1[CH:9]=[N:10][C:11]([C:14]2[CH:19]=[CH:18][C:17]([OH:20])=[CH:16][CH:15]=2)=[N:12][CH:13]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH2:21](Br)[C:22]([CH2:27]Br)([CH2:25]Br)[CH2:23]Br.[C:30](=[O:33])([O-])[O-].[K+].[K+]>CS(C)=O>[CH2:1]([C:8]1[CH:13]=[N:12][C:11]([C:14]2[CH:15]=[CH:16][C:17]([O:20][CH2:21][C:22]([CH2:27][O:33][C:30]3[CH:18]=[CH:19][C:14]([C:11]4[N:12]=[CH:13][C:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[CH:9][N:10]=4)=[CH:15][CH:16]=3)([CH2:25][O:20][C:17]3[CH:16]=[CH:15][C:14]([C:11]4[N:10]=[CH:9][C:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[CH:13][N:12]=4)=[CH:19][CH:18]=3)[CH2:23][O:20][C:17]3[CH:16]=[CH:15][C:14]([C:11]4[N:10]=[CH:9][C:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[CH:13][N:12]=4)=[CH:19][CH:18]=3)=[CH:18][CH:19]=2)=[N:10][CH:9]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]